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Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations

Mononuclear metal-peroxo species are invoked as the key intermediates in metalloenzymatic or synthetic catalysis. However, either transience or sluggishness reactivity of synthetic analogs of metal-peroxo species impedes our understanding of oxygen activation mechanism. Herein, we designed and chara...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:iScience
Egile Nagusiak: Deng, Zhihong, Wu, Peng, Cai, Yapeng, Sui, Yanheng, Chen, Zhixin, Zhang, Hong, Wang, Binju, Xia, Haiping
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Elsevier 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7399181/
https://ncbi.nlm.nih.gov/pubmed/32739835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2020.101379
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