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A Free‐Radical Prompted Barrierless Gas‐Phase Synthesis of Pentacene
A representative, low‐temperature gas‐phase reaction mechanism synthesizing polyacenes via ring annulation exemplified by the formation of pentacene (C(22)H(14)) along with its benzo[a]tetracene isomer (C(22)H(14)) is unraveled by probing the elementary reaction of the 2‐tetracenyl radical (C(18)H(1...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7383502/ https://ncbi.nlm.nih.gov/pubmed/32266773 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003402 |
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