A Free‐Radical Prompted Barrierless Gas‐Phase Synthesis of Pentacene

A representative, low‐temperature gas‐phase reaction mechanism synthesizing polyacenes via ring annulation exemplified by the formation of pentacene (C(22)H(14)) along with its benzo[a]tetracene isomer (C(22)H(14)) is unraveled by probing the elementary reaction of the 2‐tetracenyl radical (C(18)H(1...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Zhao, Long, Kaiser, Ralf I., Lu, Wenchao, Ahmed, Musahid, Evseev, Mikhail M., Bashkirov, Eugene K., Azyazov, Valeriy N., Tönshoff, Christina, Reicherter, Florian, Bettinger, Holger F., Mebel, Alexander M.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383502/
https://ncbi.nlm.nih.gov/pubmed/32266773
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003402
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