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Regio- and Stereoselective Synthesis of 1,2-Dihaloalkenes Using In-Situ-Generated ICl, IBr, BrCl, I2, and Br2
We describe a catalyst-free 1,2-trans-dihalogenation of alkynes with an unprecedented substrate scope and exclusive regio- and stereoselectivity. This versatile dihalogenation system—a combination of NX(1)S electrophile and alkali metal halide (MX(2)) in acetic acid—is applicable for diverse categor...
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| Publicado no: | Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7367077/ https://ncbi.nlm.nih.gov/pubmed/32685767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chempr.2020.03.011 |
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