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Base-Promoted Radical Azofluoromethylation of Unactivated Alkenes

The base induced reaction of aryl diazonium salts with commercially available CF(3)SO(2)Na/CF(2)HSO(2)Na allows for the generation of the corresponding diazene radicals along with fluoromethyl radicals. The addition of fluoromethyl radicals to alkenes with subsequent diazene trapping provides the az...

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Pubblicato in:Org Lett
Autori principali: Lu, Zhichao, Hennis, Olivia, Gentry, Joseph, Xu, Bo, Hammond, Gerald B.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7328341/
https://ncbi.nlm.nih.gov/pubmed/32400165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01395
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