Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling

The mononuclear zinc(II) complex cis-[ZnL(2)(H(2)O)(2)] (1; L = 4-(pyridin-3-ylcarbamoyl)benzoate) was synthesized and characterized. By soaking crystals of 1 in a mixture of DMF-H(2)O solution containing a slight excess of Cu(NO(3))(2) × 3H(2)O a transmetalation reaction occurred affording the rela...

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Vydáno v:Molecules
Hlavní autoři: Paul, Anup, Martins, Luísa M. D. R. S., Karmakar, Anirban, Kuznetsov, Maxim L., C. Guedes da Silva, M. Fátima, Pombeiro, Armando J. L.
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2020
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7321079/
https://ncbi.nlm.nih.gov/pubmed/32517273
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25112644
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