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The Nature of Triel Bonds, a Case of B and Al Centres Bonded with Electron Rich Sites

The second-order Møller–Plesset perturbation theory calculations with the aug-cc-pVTZ basis set were performed on complexes of triel species: BCl(3), BH(3), AlCl(3), and AlH(3) acting as Lewis acids through the B or Al centre with Lewis base units: NCH, N(2), NH(3), and Cl(−) anion. These complexes...

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Detalhes bibliográficos
Publicado no:Molecules
Autor principal: Grabowski, Sławomir J.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7321078/
https://ncbi.nlm.nih.gov/pubmed/32545172
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25112703
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