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Triel Bonds, π-Hole-π-Electrons Interactions in Complexes of Boron and Aluminium Trihalides and Trihydrides with Acetylene and Ethylene

MP2/aug-cc-pVTZ calculations were performed on complexes of aluminium and boron trihydrides and trihalides with acetylene and ethylene. These complexes are linked through triel bonds where the triel center (B or Al) is characterized by the Lewis acid properties through its π-hole region while π-elec...

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Detalhes bibliográficos
Publicado no:Molecules
Autor principal: Grabowski, Sławomir J.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6272408/
https://ncbi.nlm.nih.gov/pubmed/26102066
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules200611297
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