Facile Access to Dative, Single, and Double Silicon−Metal Bonds Through M−Cl Insertion Reactions of Base‐Stabilized Si(II) Cations

Silicon(II) cations can offer fascinating reactivity patterns due to their unique electronic structure: a lone pair of electrons, two empty p orbitals and a positive charge combined on a single silicon center. We now report the facile insertion of N‐heterocyclic carbene (NHC)‐stabilized silyliumylid...

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Vydáno v:Chemistry
Hlavní autoři: Frisch, Philipp, Szilvási, Tibor, Inoue, Shigeyoshi
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318344/
https://ncbi.nlm.nih.gov/pubmed/32073169
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000866
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