Selective ortho‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer

Contrary to the general belief that Pd‐catalyzed cross‐coupling at sites of severe steric hindrance are disfavored, we herein show that the oxidative addition to C−Br ortho to an adamantyl group is as favored as the corresponding adamantyl‐free system due to attractive dispersion forces. This enable...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Kalvet, Indrek, Deckers, Kristina, Funes‐Ardoiz, Ignacio, Magnin, Guillaume, Sperger, Theresa, Kremer, Marius, Schoenebeck, Franziska
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317867/
https://ncbi.nlm.nih.gov/pubmed/32065717
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001326
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