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A Photochemical Organocatalytic Strategy for the α‐Alkylation of Ketones by using Radicals
Reported herein is a visible‐light‐mediated radical approach to the α‐alkylation of ketones. This method exploits the ability of a nucleophilic organocatalyst to generate radicals upon S(N)2‐based activation of alkyl halides and blue light irradiation. The resulting open‐shell intermediates are then...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317845/ https://ncbi.nlm.nih.gov/pubmed/32053279 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915814 |
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