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Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic Os(VI)N–Pt(II) Complex
[Image: see text] Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouch...
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| Publicado no: | Inorg Chem |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2020
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7311052/ https://ncbi.nlm.nih.gov/pubmed/32227864 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c00654 |
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