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Vicinal, Double C-H Functionalization of Alcohols via an Imidate Radical-Polar Crossover Cascade
A double functionalization of vicinal sp(3) C-H bonds has been developed, wherein a β amine and γ iodide are incorporated onto an aliphatic alcohol in a single operation. This approach is enabled by an imidate radical chaperone, which selectively affords a transient β alkene that is amino-iodinated...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7299201/ https://ncbi.nlm.nih.gov/pubmed/32141741 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01318 |
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