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Disulfide Chromophores Arise from Stereoelectronic Effects

Bonds between sulfur atoms are prevalent in natural products, peptides, and proteins. Disulfide bonds have a distinct chromophore. The wavelength of their maximal absorbance varies widely, from 250 to 500 nm. Here, we demonstrate that this wavelength derives from stereoelectronic effects and is pred...

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Pubblicato in:J Phys Chem B
Autori principali: Kilgore, Henry R., Raines, Ronald T.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7293578/
https://ncbi.nlm.nih.gov/pubmed/32293886
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.0c02272
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