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Control of stereoselectivity in diverse hapalindole metabolites is mediated by cofactor induced combinatorial pairing of Stig cyclases
The stereospecific polycyclic core formation of hapalindoles and fischerindoles is controlled by the Stig cyclases through a three-step cascade involving Cope rearrangement, 6-exo-trig cyclization and a final electrophilic aromatic substitution. Here we report a comprehensive study of all currently...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7274885/ https://ncbi.nlm.nih.gov/pubmed/32052896 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201913686 |
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