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Switching on a Nontraditional Enzymatic Base – Deprotonation by Serine in the ent-Kaurene Synthase from Bradyrhizobium japonicum
Terpene synthases often catalyze complex carbocation cascade reactions. It has been previously shown that single residue switches involving replacement of a key aliphatic residue with serine or threonine can “short-circuit” such reactions, presumed to act indirectly via dipole stabilization of inter...
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| Publicat a: | ACS Catal |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7266162/ https://ncbi.nlm.nih.gov/pubmed/32489716 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b02783 |
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