An Epoxide Intermediate in Glycosidase Catalysis

[Image: see text] Retaining glycoside hydrolases cleave their substrates through stereochemical retention at the anomeric position. Typically, this involves two-step mechanisms using either an enzymatic nucleophile via a covalent glycosyl enzyme intermediate or neighboring-group participation by a s...

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發表在:ACS Cent Sci
Main Authors: Sobala, Lukasz F., Speciale, Gaetano, Zhu, Sha, Raich, Lluís, Sannikova, Natalia, Thompson, Andrew J., Hakki, Zalihe, Lu, Dan, Shamsi Kazem Abadi, Saeideh, Lewis, Andrew R., Rojas-Cervellera, Víctor, Bernardo-Seisdedos, Ganeko, Zhang, Yongmin, Millet, Oscar, Jiménez-Barbero, Jesús, Bennet, Andrew J., Sollogoub, Matthieu, Rovira, Carme, Davies, Gideon J., Williams, Spencer J.
格式: Artigo
語言:Inglês
出版: American Chemical Society 2020
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7256955/
https://ncbi.nlm.nih.gov/pubmed/32490192
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.0c00111
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