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Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh(3))(Br)](2)(μ,η(2)-C(4)H(3)N(2))(2), [Pd(Br)](2)(μ,η(2)-Hdppa)(2), and [{Pd(PPh(3))(CH(3)CN)}(2)(μ,η(2)-C(4)H(3)N(2))(2)][BF(4)](2)
In a refluxing chloroform solution, the η(1)-pyrimidinyl {pyrimidinyl = C(4)H(3)N(2)} palladium complex [Pd(PPh(3))(2)(η(1)-C(4)H(3)N(2))(Br)], 1 exhibited intermolecular displacement of two triphenylphosphine ligands to form the doubly bridged η(2)-pyrimidinyl Dipalladium complex [Pd(PPh(3))(Br)](2...
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| Publicado no: | Molecules |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7248739/ https://ncbi.nlm.nih.gov/pubmed/32349398 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25092035 |
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