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Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and their Application to Catalyst-Controlled C—H Functionalization
Catalyst-controlled C—H functionalization by means of the C—H insertion chemistry of rhodium carbenes has become a powerful synthetic method. The key requirements for the development of this chemistry are donor/acceptor carbenes and the chiral dirhodium tetracarboxylate catalysts. This perspective w...
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| Publicado en: | J Org Chem |
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| Autor principal: | |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7232105/ https://ncbi.nlm.nih.gov/pubmed/31525891 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02428 |
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