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Experimental and Computational Studies Unraveling the Peculiarity of Enolizable Oxoesters in the Organocatalyzed Mannich-Type Addition to Cyclic N-Acyl Iminium Ions

γ− and δ-Oxoesters are easily available starting materials that have been sparingly used in some organocatalyzed reactions proceeding with a high enantioselectivity. In our experimentation we found that the use of these compounds as the enolizable (nucleophilic) component in organocatalyzed Mannich-...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Menichetti, Andrea, Di Pietro, Sebastiano, Di Bussolo, Valeria, Favero, Lucilla, Pineschi, Mauro
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7221655/
https://ncbi.nlm.nih.gov/pubmed/32326095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25081903
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