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Gold Redox Catalysis with a Selenium Cation as Mild Oxidant
Gold-catalyzed alkyne and allene diselenations were developed. Excellent regioselectivity (trans) and good to excellent yields were achieved (up to 98% with 2% catalyst loading) with a wide range of substrates. Mechanistic investigation revealed the formation of a vinyl gold(I) intermediate followed...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7220824/ https://ncbi.nlm.nih.gov/pubmed/32037616 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000166 |
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