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Stereocontrolled Synthesis of the Equatorial Glycosides of 3-Deoxy-D-manno-oct-2-ulosonic Acid: Role of Side Chain Conformation

The pseudosymmetric relationship of the bacterial sialic acid, pseudaminic acid, and 3-Deoxy-D-manno-oct-2-ulosonic acid (KDO) affords the hypothesis that suitably protected KDO donors will adopt the trans,gauche conformation of their side chain and consequently be highly equatorially selective in t...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ngoje, Philemon, Crich, David
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7213052/
https://ncbi.nlm.nih.gov/pubmed/32275429
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03215
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