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Stereocontrolled Synthesis of the Equatorial Glycosides of 3-Deoxy-D-manno-oct-2-ulosonic Acid: Role of Side Chain Conformation
The pseudosymmetric relationship of the bacterial sialic acid, pseudaminic acid, and 3-Deoxy-D-manno-oct-2-ulosonic acid (KDO) affords the hypothesis that suitably protected KDO donors will adopt the trans,gauche conformation of their side chain and consequently be highly equatorially selective in t...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7213052/ https://ncbi.nlm.nih.gov/pubmed/32275429 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03215 |
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