Remote Participation during Glycosylation Reactions of Galactose Building Blocks: Direct Evidence from Cryogenic Vibrational Spectroscopy

The stereoselective formation of 1,2‐cis‐glycosidic bonds is challenging. However, 1,2‐cis‐selectivity can be induced by remote participation of C4 or C6 ester groups. Reactions involving remote participation are believed to proceed via a key ionic intermediate, the glycosyl cation. Although mechani...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Marianski, Mateusz, Mucha, Eike, Greis, Kim, Moon, Sooyeon, Pardo, Alonso, Kirschbaum, Carla, Thomas, Daniel A., Meijer, Gerard, von Helden, Gert, Gilmore, Kerry, Seeberger, Peter H., Pagel, Kevin
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187407/
https://ncbi.nlm.nih.gov/pubmed/31944510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201916245
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