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C−H Bond Cleavage Is Rate-Limiting for Oxidative C−P Bond Cleavage by the Mixed Valence Diiron-Dependent Oxygenase PhnZ
PhnZ utilizes a mixed valence diiron(II/III) cofactor and O(2) to oxidatively cleave the carbon–phosphorus bond of (R)-2-amino-1-hydroxyethylphosphonic acid to form glycine and orthophosphate. The active site residues Y24 and E27 are proposed to mediate induced-fit recognition of the substrate and a...
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| Udgivet i: | Biochemistry |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7176486/ https://ncbi.nlm.nih.gov/pubmed/31046250 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.9b00145 |
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