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Group 2 Promoted Hydrogen Release from NMe(2)H⋅BH(3): Intermediates and Catalysis
Both homo‐ and heteroleptic alkyl and amide complexes of the Group 2 elements Mg and Ca are shown to be active for the catalytic dehydrocoupling of Me(2)NH⋅BH(3). Reactions of either magnesium dialkyls or the β‐diketiminate complex [HC{(Me)CN(Dipp)}(2)MgnBu] with four or two equivalents of Me(2)NHBH...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
WILEY‐VCH Verlag
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7162034/ https://ncbi.nlm.nih.gov/pubmed/20544744 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201000127 |
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