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Synthesis and Characterization of Tantalum-Based Early-Late Heterobimetallic Complexes Supported by 2-(diphenylphosphino)pyrrolide Ligands

The synthesis of the metalloligand Ta(κ(2)-NP)(3)Cl(2) (NP = 2-diphenylphosphinopyrrolide) and its coordination chemistry with group 9 and 10 metals is reported. Treatment of Ta(κ(2)-NP)(3)Cl(2) with group 9 and 10 metals resulted in clean formation of the heterobimetallic complexes Cl(2)Ta(μ(2)-NP)...

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Detalhes bibliográficos
Publicado no:Polyhedron
Main Authors: Dunn, Peter L., Beaumier, Evan P., Tonks, Ian A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7156031/
https://ncbi.nlm.nih.gov/pubmed/32292224
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2020.114471
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