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Enantioselective Synthesis of γ-Lactams by Lewis-Base Catalyzed Sulfenoamidation of Alkenes
A method for the catalytic, enantioselective, intramolecular, 1,2-sulfenoamidation of alkenes is described. Lewis base activation of a suitable sulfur electrophile generates an enantioenriched, thiiranium ion intermediate from a β,γ-unsaturated sulfonyl carboxamide. This intermediate is subsequently...
Guardat en:
| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7127933/ https://ncbi.nlm.nih.gov/pubmed/31858805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b04347 |
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