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Enantioselective Synthesis of γ-Lactams by Lewis-Base Catalyzed Sulfenoamidation of Alkenes
A method for the catalytic, enantioselective, intramolecular, 1,2-sulfenoamidation of alkenes is described. Lewis base activation of a suitable sulfur electrophile generates an enantioenriched, thiiranium ion intermediate from a β,γ-unsaturated sulfonyl carboxamide. This intermediate is subsequently...
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| Udgivet i: | Org Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7127933/ https://ncbi.nlm.nih.gov/pubmed/31858805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b04347 |
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