Pd‐Catalyzed Asymmetric N‐Allylation of Amino Acid Esters with Exceptional Levels of Catalyst Control: Stereo‐Divergent Synthesis of ProM‐15 and Related Bicyclic Dipeptide Mimetics

A general and powerful method for the stereo‐controlled Pd‐catalyzed N‐allylation of amino acid esters is reported, as a previously largely unsolved synthetic challenge. Employing a new class of tartaric acid‐derived C (2)‐symmetric chiral diphosphane ligands the developed asymmetric amination proto...

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Publicado en:Chemistry
Autores principales: Dohmen, Stephan, Reiher, Martin, Albat, Dominik, Akyol, Sema, Barone, Matthias, Neudörfl, Jörg‐Martin, Kühne, Ronald, Schmalz, Hans‐Günther
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7078984/
https://ncbi.nlm.nih.gov/pubmed/31961029
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000307
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