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Selenophosphoramide-catalyzed diamination and oxyamination of alkenes
A new selenophosphoramide-catalyzed diamination of terminal- and trans-1,2-disubstituted olefins is presented. Key to the success of this transformation was the introduction of a fluoride scavenger, trimethylsilyl trifluoromethanesulfonate (TMSOTf), to prevent a competitive syn-elimination pathway,...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7069249/ https://ncbi.nlm.nih.gov/pubmed/32206288 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05335b |
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