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Interconversion and reactivity of manganese silyl, silylene, and silene complexes
Manganese disilyl hydride complexes [(dmpe)(2)MnH(SiH(2)R)(2)] (4(Ph): R = Ph, 4(Bu): R = (n)Bu) reacted with ethylene to form silene hydride complexes [(dmpe)(2)MnH(RHSi[double bond, length as m-dash]CHMe)] (6(Ph,H): R = Ph, 6(Bu,H): R = (n)Bu). Compounds 6(R,H) reacted with a second equivalent of...
Shranjeno v:
| izdano v: | Chem Sci |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7069235/ https://ncbi.nlm.nih.gov/pubmed/32206252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04513a |
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