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Chemoselective Tertiary C—H Hydroxylation for Late-Stage Functionalization with Mn(PDP)/Chloroacetic Acid Catalysis
Aromatic and heterocyclic functionality are ubiquitous in pharmaceuticals. Herein, we disclose a new Mn(PDP)catalyst system using chloroacetic acid additive capable of chemoselectively oxidizing remote tertiary C(sp(3))—H bonds in the presence of a broad range of aromatic and heterocyclic moieties....
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| Publicado no: | Adv Synth Catal |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7066868/ https://ncbi.nlm.nih.gov/pubmed/32165875 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201901472 |
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