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Quaternary–centre–guided synthesis of complex polycyclic terpenes
The presence of a quaternary centre—a carbon with four other carbons bonded to it—in any given molecule can have a substantial chemical and biological impact. In many cases, it can enable otherwise challenging chemistry. For example, quaternary centres induce large rate enhancements in cyclization r...
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| Publicado no: | Nature |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7062202/ https://ncbi.nlm.nih.gov/pubmed/31022719 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41586-019-1179-2 |
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