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Synthesis of quaternary centres by single electron reduction and alkylation of alkylsulfones

A new method for the generation of tertiary radicals through single electron reduction of alkylsulfones promoted by Zn and 1,10-phenanthroline has been developed. These radicals could be employed in the Giese reaction, affording structurally diverse quaternary products in good yields. With the high...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Nambo, Masakazu, Tahara, Yasuyo, Yim, Jacky C.-H., Yokogawa, Daisuke, Crudden, Cathleen M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179647/
https://ncbi.nlm.nih.gov/pubmed/34168761
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00133g
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