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Understanding the Role of Electron Donors in the Reaction Catalyzed by TsrM, a Cobalamin-Dependent Radical S-Adenosylmethionine Methylase

The cobalamin-dependent radical S-adenosylmethionine (SAM) enzyme TsrM catalyzes the methylation of C2 of L-tryptophan to form 2-methyltryptophan during the biosynthesis of thiostrepton A. Although TsrM is a member of the radical SAM superfamily, unlike all other annotated members, it does not catal...

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Detalhes bibliográficos
Publicado no:J Biol Inorg Chem
Main Authors: Blaszczyk, Anthony J., Knox, Hayley L., Booker, Squire J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7061315/
https://ncbi.nlm.nih.gov/pubmed/31350635
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-019-01689-8
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