Rational selection of co-catalysts for the deaminative hydrogenation of amides

The catalytic hydrogenation of amides is an atom economical method to synthesize amines. Previously, it was serendipitously discovered that the combination of a secondary amide co-catalyst with ((iPr)PNP)Fe(H)(CO) ((iPr)PNP = N[CH(2)CH(2)(P(i)Pr(2))](2)(–)), results in a highly active base metal sys...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Artús Suàrez, Lluís, Jayarathne, Upul, Balcells, David, Bernskoetter, Wesley H., Hazari, Nilay, Jaraiz, Martín, Nova, Ainara
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2020
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7059200/
https://ncbi.nlm.nih.gov/pubmed/32190278
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03812d
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