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Stable group 8 metal porphyrin mono- and bis(dialkylcarbene) complexes: synthesis, characterization, and catalytic activity

Alkyl-substituted carbene (CHR or CR(2), R = alkyl) complexes have been extensively studied for alkylcarbene (CHR) ligands coordinated with high-valent early transition metal ions (a.k.a. Schrock carbenes or alkylidenes), yet dialkylcarbene (CR(2)) complexes remain less developed with bis(dialkylcar...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Wang, Hai-Xu, Wan, Qingyun, Low, Kam-Hung, Zhou, Cong-Ying, Huang, Jie-Sheng, Zhang, Jun-Long, Che, Chi-Ming
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7047983/
https://ncbi.nlm.nih.gov/pubmed/32180931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05432d
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