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Transfer Hydrogenation of Ketones Catalyzed by Symmetric Imino-N-heterocyclic Carbene Co(III) Complexes

[Image: see text] The synthesis of new moisture-sensitive imine-functionalized N-heterocyclic carbene (NHC) precursor salts [1-(2-[(hydroxyl-benzylidene)-amino]-ethyl)-3-R-3H-imidazole-1-ium bromide; R = methyl (1a), ethyl (1b), and benzyl (1c)] is reported. Subsequent deprotonation of 1a–c and coor...

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Foilsithe in:ACS Omega
Main Authors: Abubakar, Samaila, Bala, Muhammad D.
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Chemical Society 2020
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7033672/
https://ncbi.nlm.nih.gov/pubmed/32095690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b03181
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