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On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions
Attempts have been made to prepare salts with the labile tris(trimethylsilyl)chalconium ions, [(Me(3)Si)(3)E](+) (E=O, S), by reacting [Me(3)Si‐H‐SiMe(3)][B(C(6)F(5))(4)] and Me(3)Si[CB] (CB(−)=carborate=[CHB(11)H(5)Cl(6)](−), [CHB(11)Cl(11)](−)) with Me(3)Si‐E‐SiMe(3). In the reaction of Me(3)Si‐O‐...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7028070/ https://ncbi.nlm.nih.gov/pubmed/31738450 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904403 |
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