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Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes
Phosphine‐stabilized germaborenes featuring an unprecedented Ge=B double bond with short B⋅⋅⋅Ge contacts of 1.886(2) (4) and 1.895(3) Å (5) were synthesized starting from an intramolecular germylene–phosphine Lewis pair (1). After oxidative addition of boron trihalides BX(3) (X=Cl, Br), the addition...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7028040/ https://ncbi.nlm.nih.gov/pubmed/31804742 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914608 |
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