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Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes

Phosphine‐stabilized germaborenes featuring an unprecedented Ge=B double bond with short B⋅⋅⋅Ge contacts of 1.886(2) (4) and 1.895(3) Å (5) were synthesized starting from an intramolecular germylene–phosphine Lewis pair (1). After oxidative addition of boron trihalides BX(3) (X=Cl, Br), the addition...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Raiser, Dominik, Sindlinger, Christian P., Schubert, Hartmut, Wesemann, Lars
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7028040/
https://ncbi.nlm.nih.gov/pubmed/31804742
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914608
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