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Nickel-catalyzed C–H alkylation of indoles with unactivated alkyl chlorides: evidence of a Ni(i)/Ni(iii) pathway

A mild and efficient nickel-catalyzed method for the coupling of unactivated primary and secondary alkyl chlorides with the C–H bond of indoles and pyrroles is described which demonstrates a high level of chemo and regioselectivity. The reaction tolerates numerous functionalities, such as halide, al...

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Publicat a:Chem Sci
Autors principals: Pandey, Dilip K., Ankade, Shidheshwar B., Ali, Abad, Vinod, C. P., Punji, Benudhar
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7017866/
https://ncbi.nlm.nih.gov/pubmed/32110305
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01446b
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