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Preferential binding of unsaturated hydrocarbons in aryl-bisimidazolium·cucurbit[8]uril complexes furbishes evidence for small-molecule π–π interactions

Whilst cucurbit[n]urils (CBn) have been utilized in gas encapsulation, only the smaller CBn (n = 5 and 6) have utility given their small cavity size. In this work, we demonstrate that the large cavity of CB8 can be tailored for gaseous and volatile hydrocarbon encapsulation by restricting its intern...

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Publicat a:Chem Sci
Autors principals: Barrow, Steven J., Assaf, Khaleel I., Palma, Aniello, Nau, Werner M., Scherman, Oren A.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7006508/
https://ncbi.nlm.nih.gov/pubmed/32110310
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03282g
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