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Preferential binding of unsaturated hydrocarbons in aryl-bisimidazolium·cucurbit[8]uril complexes furbishes evidence for small-molecule π–π interactions

Whilst cucurbit[n]urils (CBn) have been utilized in gas encapsulation, only the smaller CBn (n = 5 and 6) have utility given their small cavity size. In this work, we demonstrate that the large cavity of CB8 can be tailored for gaseous and volatile hydrocarbon encapsulation by restricting its intern...

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Библиографические подробности
Опубликовано в: :Chem Sci
Главные авторы: Barrow, Steven J., Assaf, Khaleel I., Palma, Aniello, Nau, Werner M., Scherman, Oren A.
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2019
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC7006508/
https://ncbi.nlm.nih.gov/pubmed/32110310
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03282g
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