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A macrocyclic oligofuran: synthesis, solid state structure and electronic properties
We report the first π-conjugated macrocyclic system with an oligofuran backbone. The calculated HOMO–LUMO gap is similar to that of the corresponding linear polymer, indicating a remarkable electron delocalization. The X-ray structure reveals a planar conformation, in contrast to the twisted conform...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7003964/ https://ncbi.nlm.nih.gov/pubmed/32055302 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03247a |
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