Chiroptical inversion of a planar chiral redox-switchable rotaxane

A tetrathiafulvalene (TTF)-containing crown ether macrocycle with C(s) symmetry was designed to implement planar chirality into a redox-active [2]rotaxane. The directionality of the macrocycle atom sequence together with the non-symmetric axle renders the corresponding [2]rotaxane mechanically plana...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Gaedke, Marius, Witte, Felix, Anhäuser, Jana, Hupatz, Henrik, Schröder, Hendrik V., Valkonen, Arto, Rissanen, Kari, Lützen, Arne, Paulus, Beate, Schalley, Christoph A.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2019
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7003955/
https://ncbi.nlm.nih.gov/pubmed/32055357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03694f
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