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The Critical Role of Reductive Steps in the Nickel‐Catalyzed Hydrogenolysis and Hydrolysis of Aryl Ether C−O Bonds
The hydrogenolysis of the aromatic C−O bond in aryl ethers catalyzed by Ni was studied in decalin and water. Observations of a significant kinetic isotope effect (k (H)/k (D)=5.7) for the reactions of diphenyl ether under H(2) and D(2) atmosphere and a positive dependence of the rate on H(2) chemica...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7003888/ https://ncbi.nlm.nih.gov/pubmed/31512341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909551 |
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