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Peptide-Catalyzed Fragment Couplings that Form Axially Chiral Non-C(2)-Symmetric Biaryls
We have demonstrated that small, modular, tetrameric peptides featuring a Lewis-basic residue, β-dimethylaminoalanine (Dmaa), are capable of atroposelectively coupling naphthols and ester-bearing quinones, yielding non-C(2)-symmetric BINOL-type scaffolds with good yields and enantioselectivities. Th...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7002259/ https://ncbi.nlm.nih.gov/pubmed/31793137 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201913563 |
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