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Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes
[Image: see text] We report a series of titanium and zirconium complexes supported by dianionic amidophosphine–borane ligands, synthesized by amine elimination and salt metathesis reactions. The Ti(IV) complex [{Ph(2)P(BH(3))N}(2)C(6)H(4)Ti(NMe(2))(2)] (1) was obtained by the reaction between tetrak...
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| Publicado no: | ACS Omega |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2020
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6990649/ https://ncbi.nlm.nih.gov/pubmed/32010834 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b03598 |
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